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(S)-(-)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)

(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
产品编号:3331486
规格:≥97%, optical purity ee: ≥99%
CAS NO:133545-17-2
包装规格:50 G,100 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
333148650 G126660
3331486100 G171700
产品别名

133545-17-2

(S)-(-)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)

(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

(S)-(-)-MeO-BIPHEP

SL-A101-2

(S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl

(S)-(-)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C38H32O2P2
Molecular weight
582.61
Beilstein
4790083
MDL number
MFCD03095430
PubChem Substance ID【PubChem化学物质编号】
24857759
NACRES
NA.22
General description【一般描述】
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application【应用】
Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Atropisomeric MeOBIPHEP ligands

  • C–C coupling reactions
  • Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides
  • Enantioselective hydrogenation of a-amino-ß-keto ester hydrochlorides catalyzed by an iridium complex
  • Asymmetric hydrogenation of aromatic ketones
产品性质
Quality Level【质量水平】
100
Assay【测定】
≥97%
optical purity【光学纯度】
ee: ≥99%
greener alternative product characteristics【环保替代产品特性】
Catalysis
Learn more about the Principles of Green Chemistry.
greener alternative category【环保替代产品分类】
Aligned
SMILES string
COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
InChI
1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key
KRJVQCZJJSUHHO-UHFFFAOYSA-N
packaging【包装】
1, 5 g in glass bottle
500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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