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苯氧乙酰氯

Phenoxyacetyl Chloride
产品编号:3057126
规格:98%
CAS NO:701-99-5
包装规格:50g,250g,1000g
产品类别:进口试剂
品牌:Alfa Aesar
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
305712650g1115
3057126250g3600
30571261000g10820
产品别名

701-99-5

苯氧乙酰氯

Phenoxyacetyl Chloride

基本信息
应用
Acylation of D- and DL-WV with phenoxyacetyl chloride, followed by cleavage of the t-butyl ester,afforded the penultimate penicilloic acids. Phenoxyacetyl chloride was used in the synthesis of series of macrocyclic bis-β-lactams, 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester, N-protected guanosine derivatives, useful in RNA synthesis, phenyloxyketene, for cycloaddition to imines leading to β-lactams. Treatment of iminophosphoranes with phenoxyacetyl chloride afforded respectively the trans- and cis-3-(acylamino)-p-lactams. By the oxidative addition of stannous fluoride to allyliodide, with 1, 2-O-isopropylidene-D-glyceraldehyde and phenoxyacetyl chloride results in the predominant formation of erythro homoallylester, which is in turn converted into 2-deoxy-D-ribose. The 4-disubstituted P-lactams (4a-c and 6a-b) were prepared through the reaction of N,N-diphenylhydrazones and N-methyl-N-phenylhydrazones of ketones with phenoxyacetyl chloride/Et3N in dichloromethane.
备注
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.
MDL
MFCD00000726
EINECS
211-862-4
分子式
C8H7ClO2
分子量
170.60
沸点
225-226°
闪点
108°(226°F)
密度
1.235
折射率
1.5340
灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
形态
Liquid
溶解性
Reacts with water.
Beilstein
607585
危险类别
14-34
Reacts violently with water.Causes burns.
安全信息
安全等级
8-20-23-26-30-36/37/39-45-60
Keep container dry.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste
欧盟危险品标志
 
TSCA
GHS危害和防范说明
GHS符号
 
Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
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